Wow. I'm only a (very) casual fan of both of them but that sounds like quite the show. Have a setlist for us?
Unfortunately not...I didn't have the presence of mind to write one down at the time. I will try to remember ones off the top of my head, though... Please bear in mind the fact that I am terrible at remembering/knowing song titles. Some of these songs just Buddy played, some just Emmylou, but the vast majority were both of them.
All My Tears (opened the concert with this one)
Orphan Girl
Here I Am
Strong Hand (for June)
Cup of Kindness
That's How I Got to Memphis
Light of the Stable
Together Again
Does My Ring Burn Your Finger
Don't Tell Me
There's A Higher Power
Worry Too Much
Michaelangelo
My Antonia
Love Hurts
Boulder to Birmingham (encore)
Imagine (encore)
They played many, many more...it was about a 2.5 hour concert...but those are the only ones I can come up with right now. I may remember more later.